<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="1.3" xml:lang="en">
  <front>
    <journal-meta>
      <journal-id journal-id-type="publisher-id">Ecological Safety of Coastal and Shelf Zones of Sea</journal-id>
      <journal-title-group>
        <journal-title>Ecological Safety of Coastal and Shelf Zones of Sea</journal-title>
      </journal-title-group>
      <issn publication-format="print">2413-5577</issn>
    </journal-meta>
    <article-meta>
      <article-id pub-id-type="publisher-id">20260103</article-id>
      
      <article-categories>
        <subj-group subj-group-type="article-type">
          <subject>Research Article</subject>
        </subj-group>
      </article-categories>

      <title-group>
        <article-title>Hydrocarbons in the Water and Suspended Matter of the Coastal Water Areas of Crimea and Krasnodar Krai after the Fuel Oil Spill in December 2024</article-title>
      </title-group>

      <contrib-group>
        <contrib contrib-type="author">
          <name>
            <surname>Tikhonova</surname>
            <given-names>E. A.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <email>tikhonova_ea@ibss-ras.ru</email>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Soloveva</surname>
            <given-names>O. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Mironov</surname>
            <given-names>O. A.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Alyomov</surname>
            <given-names>S. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Klycheva (Tkachenko)</surname>
            <given-names>Yu. S.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
        <contrib contrib-type="author">
          <name>
            <surname>Frolkin</surname>
            <given-names>G. V.</given-names>
          </name>
          <address>
            <country country="RU">Russian Federation</country>
          </address>
          <xref ref-type="aff" rid="aff1"/>
        </contrib>
      </contrib-group>

      <aff id="aff1">
        <institution>A. O. Kovalevsky Institute of Biology of the Southern Seas of RAS</institution>
        <addr-line>Sevastopol</addr-line>
        <country country="RU">Russia</country>
      </aff>

      <pub-date date-type="pub" iso-8601-date="2026-03-31" publication-format="electronic">
        <day>31</day>
        <month>03</month>
        <year>2026</year>
      </pub-date>
      <volume>2026</volume>
      <issue>1</issue>
      <fpage>52</fpage>
      <lpage>72</lpage>

      <history>
        <date date-type="received" iso-8601-date="2025-09-19">
          <day>19</day>
          <month>09</month>
          <year>2025</year>
        </date>
        <date date-type="rev-recd" iso-8601-date="2025-12-18">
          <day>18</day>
          <month>12</month>
          <year>2025</year>
        </date>
        <date date-type="accepted" iso-8601-date="2025-10-06">
          <day>06</day>
          <month>10</month>
          <year>2025</year>
        </date>
      </history>

      <permissions>
        <copyright-statement>Copyright © 2026, E. A. Tikhonova, O. V. Soloveva, O. A. Mironov, S. V. Alyomov, Yu. S. Klycheva (Tkachenko), G. V. Frolkin</copyright-statement>
        <copyright-year>2026</copyright-year>
        <copyright-holder>E. A. Tikhonova, O. V. Soloveva, O. A. Mironov, S. V. Alyomov, Yu. S. Klycheva (Tkachenko), G. V. Frolkin</copyright-holder>
        <ali:free_to_read xmlns:ali="http://www.niso.org/schemas/ali/1.0/"/>
        <license>
          <ali:license_ref xmlns:ali="http://www.niso.org/schemas/ali/1.0/">https://creativecommons.org/licenses/by-nc/4.0/</ali:license_ref>
        </license>
      </permissions>

      <self-uri xlink:href="https://ecological-safety.ru/en/repository/issues/2026/01/03/" xlink:title="Page of article">https://ecological-safety.ru/en/repository/issues/2026/01/03/</self-uri>

      <abstract>
        <p>As a result of the fuel oil spill from Volgoneft-212 and Volgoneft-239 tankers in the Kerch Strait on 15 December 2024, the coast of Crimea and the Krasnodar Krai was polluted. The aim of the work is to study hydrocarbon pollution of water and suspended matter in the coastal waters of the Kerch Peninsula and Krasnodar Krai affected by fuel oil emissions from December 2024 to January 2025. Although in the first days after the tanker accident (16–18 December 2024) the hydrocarbon content in the water exceeded the MPC (0.05 mg·L⁻¹) at 70% of the stations, the n-alkanes composition and marker values indicated that the main sources of hydrocarbons in the water and suspended matter of the study water area were natural sources. Signs of degraded petroleum products were noted, indicating chronic oil pollution of the water area. During the petroleum product emissions (January 2025), average hydrocarbon concentrations in the coastal waters of the Kerch Peninsula and Krasnodar Krai did not exceed MPC. The hydrocarbon content in suspended matter in the study area ranged from 13 to 67 μg·L⁻¹, which can be characterised as high. The distribution and composition of n-alkanes in suspended matter in January 2025 indicated probable oil pollution. An analysis of hydrocarbon genesis markers confirmed this conclusion. Thus, the fuel oil pollution that arrived by January 2025 did not cause an increase in hydrocarbon concentrations in the water. In January 2025, evidence of oil pollution was detected only in suspended matter in seawater. Given that the fuel oil spill had a certain impact on individual components of the coastal ecosystem, further studies are needed to assess the long-term impact of hydrocarbons on the ecosystem of these waters.</p>
      </abstract>

      <kwd-group>
        <kwd>coastal waters</kwd>
        <kwd>fuel oil spill</kwd>
        <kwd>petroleum hydrocarbons</kwd>
        <kwd>petroleum pollution</kwd>
        <kwd>seawater</kwd>
        <kwd>suspended matter</kwd>
        <kwd>Black Sea</kwd>
      </kwd-group>

      <funding-group>
        <funding-statement>This work was carried out within the framework of the state assignment on the topic "The state of the marine environment and its capacity for self-purification in the coastal areas of the Crimean Peninsula and Krasnodar Krai after the oil spill in December 2024" (FNNZ-2026-0016).</funding-statement>
      </funding-group>
    </article-meta>
  </front>

  <body>
    <p>Article text not included.</p>
  </body>

  <back>
    <ref-list>
      <title>REFERENCES</title>
      <ref id="B1">
        <label>1.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Ivanov</surname><given-names>A.Yu.</given-names></name>
            <name><surname>Kucheiko</surname><given-names>A.A.</given-names></name>
            <name><surname>Filimonova</surname><given-names>N.A.</given-names></name>
            <name><surname>Kucheiko</surname><given-names>A.Yu.</given-names></name>
            <name><surname>Evtushenko</surname><given-names>N.V.</given-names></name>
            <name><surname>Terleeva</surname><given-names>N.V.</given-names></name>
            <name><surname>Uskova</surname><given-names>A.A.</given-names></name>
          </person-group>
          <article-title>Spatial and Temporal Distribution of Oil Spills in the Black Sea and the Caspian Sea Based on SAR Images: Comparative Analysis</article-title>
          <source>Issledovanie Zemli iz Kosmosa</source>
          <year>2017</year>
          <issue>2</issue>
          <fpage>13</fpage>
          <lpage>25</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B2">
        <label>2.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Tikhonova</surname><given-names>E.A.</given-names></name>
            <name><surname>Burdiyan</surname><given-names>N.V.</given-names></name>
            <name><surname>Soloveva</surname><given-names>O.V.</given-names></name>
            <name><surname>Doroshenko</surname><given-names>Ju.V.</given-names></name>
          </person-group>
          <article-title>Chemical and Microbiological Parameters of the Kerch Strait Sea Bottom Sediments after the Accident of "Volgoneft-139" Ship</article-title>
          <source>Environmental Protection in Oil and Gas Complex</source>
          <year>2015</year>
          <issue>4</issue>
          <fpage>12</fpage>
          <lpage>16</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B3">
        <label>3.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="editor">
            <name><surname>Korpakova</surname><given-names>I.G.</given-names></name>
            <name><surname>Agapov</surname><given-names>S.A.</given-names></name>
          </person-group>
          <source>The Oil Spill Accident in the Kerch Strait: Its Effects on the Water Ecosystems</source>
          <publisher-loc>Rostov-na-Donu</publisher-loc>
          <publisher-name>FSUE AZNIIRKH</publisher-name>
          <year>2008</year>
          <size units="pages">229</size>
        </element-citation>
      </ref>
      <ref id="B4">
        <label>4.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Matishov</surname><given-names>G.G.</given-names></name>
            <name><surname>Berdnikov</surname><given-names>S.V.</given-names></name>
            <name><surname>Savitsky</surname><given-names>R.M.</given-names></name>
          </person-group>
          <source>Ecosystem Monitoring and Assessment of the Impact of Oil Spills in the Kerch Strait. Ship Accidents in November 2007</source>
          <publisher-loc>Rostov-on-Don</publisher-loc>
          <publisher-name>Yuzhny Nauchny Zentr RAN</publisher-name>
          <year>2008</year>
          <size units="pages">80</size>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B5">
        <label>5.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Kuznetsov</surname><given-names>A.N.</given-names></name>
            <name><surname>Fedorov</surname><given-names>Yu.A.</given-names></name>
            <name><surname>Zagranitchny</surname><given-names>K.A.</given-names></name>
          </person-group>
          <article-title>About the Results of Three-Year Monitoring of a Fuel Oil Spill in the Kerch Strait</article-title>
          <source>Bulletin of Higher Educational Institutions. North Caucasus Region. Natural Sciences</source>
          <year>2011</year>
          <issue>4</issue>
          <fpage>90</fpage>
          <lpage>95</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B6">
        <label>6.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="editor">
            <name><surname>Mironov</surname><given-names>O.G.</given-names></name>
            <name><surname>Alyomov</surname><given-names>S.V.</given-names></name>
          </person-group>
          <source>Sanitary and Biological Studies of the South-Western Crimea Coastal Waters at the Beginning of XXI Century</source>
          <publisher-loc>Simferopol</publisher-loc>
          <publisher-name>ARIAL</publisher-name>
          <year>2018</year>
          <size units="pages">276</size>
          <pub-id pub-id-type="doi">10.21072/978-5-907118-89-8</pub-id>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B7">
        <label>7.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Nemirovskaya</surname><given-names>I.A.</given-names></name>
          </person-group>
          <source>Oil in the Ocean (Pollution and Natural Flow)</source>
          <publisher-loc>Moscow</publisher-loc>
          <publisher-name>Nauchny Mir</publisher-name>
          <year>2013</year>
          <size units="pages">432</size>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B8">
        <label>8.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Tashlikova</surname><given-names>N.A.</given-names></name>
            <name><surname>Kuklin</surname><given-names>A.P.</given-names></name>
            <name><surname>Bazarova</surname><given-names>B.B.</given-names></name>
          </person-group>
          <article-title>Primary Production of Phytoplankton, Epiphytic Seaweed and the Higher Water Plants in the Channels of the Selenga River Delta</article-title>
          <source>Bulletin of KSAU</source>
          <year>2009</year>
          <issue>9</issue>
          <fpage>106</fpage>
          <lpage>112</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B9">
        <label>9.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Bieger</surname><given-names>T.</given-names></name>
            <name><surname>Abrajano</surname><given-names>T.A.</given-names></name>
            <name><surname>Hellou</surname><given-names>J.</given-names></name>
          </person-group>
          <article-title>Generation of Biogenic Hydrocarbons During a Spring Bloom in Newfoundland Coastal (NW Atlantic) Waters</article-title>
          <source>Organic Geochemistry</source>
          <year>1997</year>
          <volume>26</volume>
          <issue>3-4</issue>
          <fpage>207</fpage>
          <lpage>218</lpage>
          <pub-id pub-id-type="doi">10.1016/S0146-6380(96)00159-3</pub-id>
        </element-citation>
      </ref>
      <ref id="B10">
        <label>10.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Nemirovskaya</surname><given-names>I.A.</given-names></name>
          </person-group>
          <article-title>Distribution and Origin of Hydrocarbons on a Transarctic Transect</article-title>
          <source>Oceanology</source>
          <year>2021</year>
          <volume>61</volume>
          <issue>2</issue>
          <fpage>183</fpage>
          <lpage>192</lpage>
          <pub-id pub-id-type="doi">10.1134/S0001437021020144</pub-id>
        </element-citation>
      </ref>
      <ref id="B11">
        <label>11.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Tikhonova</surname><given-names>E.A.</given-names></name>
            <name><surname>Burdiyan</surname><given-names>N.V.</given-names></name>
            <name><surname>Soloveva</surname><given-names>O.V.</given-names></name>
          </person-group>
          <article-title>The Chemical-Microbiological Characteristics of Sea Water and Bottom Sediments of the Kerch Strait and Adjacent Water Areas</article-title>
          <source>Marine Biological Journal</source>
          <year>2017</year>
          <volume>2</volume>
          <issue>3</issue>
          <fpage>75</fpage>
          <lpage>85</lpage>
          <pub-id pub-id-type="doi">10.21072/mbj.2017.02.3.07</pub-id>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B12">
        <label>12.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Yáñez-Arancibia</surname><given-names>A.</given-names></name>
            <name><surname>Day</surname><given-names>J.</given-names></name>
          </person-group>
          <article-title>Ecological Characterization of Terminos Lagoon. A Tropical Lagoon-Estuarine System in the Southern Gulf of Mexico</article-title>
          <source>Oceanologica Acta</source>
          <year>1982</year>
          <volume>5</volume>
          <issue>4</issue>
          <fpage>431</fpage>
          <lpage>440</lpage>
        </element-citation>
      </ref>
      <ref id="B13">
        <label>13.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Wang</surname><given-names>X.-C.</given-names></name>
            <name><surname>Sun</surname><given-names>S.</given-names></name>
            <name><surname>Ma</surname><given-names>H.-Q.</given-names></name>
            <name><surname>Liu</surname><given-names>Y.</given-names></name>
          </person-group>
          <article-title>Sources and Distribution of Aliphatic and Polyaromatic Hydrocarbons in Sediments of Jiaozhou Bay. Qingdao. China</article-title>
          <source>Marine Pollution Bulletin</source>
          <year>2005</year>
          <volume>52</volume>
          <issue>2</issue>
          <fpage>129</fpage>
          <lpage>138</lpage>
          <pub-id pub-id-type="doi">10.1016/j.marpolbul.2005.08.010</pub-id>
        </element-citation>
      </ref>
      <ref id="B14">
        <label>14.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Ficken</surname><given-names>K.J.</given-names></name>
            <name><surname>Li</surname><given-names>B.</given-names></name>
            <name><surname>Swain</surname><given-names>D.L.</given-names></name>
            <name><surname>Eglniton</surname><given-names>G.</given-names></name>
          </person-group>
          <article-title>An N-Alkane Proxy for the Sedimentary Input of Submerged / Floating Freshwater Aquatic Macrophytes</article-title>
          <source>Organic Geochemistry</source>
          <year>2000</year>
          <volume>31</volume>
          <issue>7-8</issue>
          <fpage>745</fpage>
          <lpage>749</lpage>
          <pub-id pub-id-type="doi">10.1016/S0146-6380(00)00081-4</pub-id>
        </element-citation>
      </ref>
      <ref id="B15">
        <label>15.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Sapozhnikov</surname><given-names>V.V.</given-names></name>
            <name><surname>Arzhanova</surname><given-names>N.V.</given-names></name>
            <name><surname>Lapina</surname><given-names>N.М.</given-names></name>
            <name><surname>Agatova</surname><given-names>А.I.</given-names></name>
            <name><surname>Torgunova</surname><given-names>N.I.</given-names></name>
            <name><surname>Zozulya</surname><given-names>N.М.</given-names></name>
            <name><surname>Bondarenko</surname><given-names>L.G.</given-names></name>
            <name><surname>Vishnevsky</surname><given-names>S.L.</given-names></name>
            <name><surname>Radchenko</surname><given-names>S.V.</given-names></name>
            <etal/>
          </person-group>
          <article-title>Complex Ecological Studies in Kerch Strait and Taman' Bight after Oil Spill (2007–2010)</article-title>
          <source>Trudy VNIRO</source>
          <year>2013</year>
          <volume>150</volume>
          <fpage>65</fpage>
          <lpage>77</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B16">
        <label>16.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Nemirovskaya</surname><given-names>I.A.</given-names></name>
            <name><surname>Khaustov</surname><given-names>A.P.</given-names></name>
            <name><surname>Redina</surname><given-names>M.M.</given-names></name>
          </person-group>
          <article-title>Distribution and Genesis of Hydrocarbons in Water and Sediments of the Kerch Strait</article-title>
          <source>Geochemistry International</source>
          <year>2022</year>
          <volume>60</volume>
          <issue>1</issue>
          <fpage>43</fpage>
          <lpage>51</lpage>
          <pub-id pub-id-type="doi">10.1134/S0016702922010098</pub-id>
        </element-citation>
      </ref>
      <ref id="B17">
        <label>17.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Mead</surname><given-names>R.</given-names></name>
            <name><surname>Xu</surname><given-names>Yu.</given-names></name>
            <name><surname>Chong</surname><given-names>J.</given-names></name>
            <name><surname>Jaffé</surname><given-names>R.</given-names></name>
          </person-group>
          <article-title>Sediment and Soil Organic Matter Source Assessment as Revealed by the Molecular Distribution and Carbon Isotopic Composition of N-Alkanes</article-title>
          <source>Organic Geochemistry</source>
          <year>2005</year>
          <volume>36</volume>
          <issue>3</issue>
          <fpage>363</fpage>
          <lpage>370</lpage>
          <pub-id pub-id-type="doi">10.1016/j.orggeochem.2004.10.003</pub-id>
        </element-citation>
      </ref>
      <ref id="B18">
        <label>18.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Simoneit</surname><given-names>B.R.T.</given-names></name>
            <name><surname>Pisani</surname><given-names>O.</given-names></name>
            <name><surname>Ekpo</surname><given-names>B.O.</given-names></name>
            <name><surname>Fubara</surname><given-names>E.P.</given-names></name>
            <name><surname>Nna</surname><given-names>P.J.</given-names></name>
            <name><surname>Ekpa</surname><given-names>O.D.</given-names></name>
          </person-group>
          <article-title>Lipid Biomarker Analysis of Suspended Particulate Matter from the Great Kwa River, SE Nigeria: Origins and Environmental Implications of Biogenic and Anthropogenic Organic Compounds</article-title>
          <source>Aquatic Geochemistry</source>
          <year>2017</year>
          <volume>23</volume>
          <issue>2</issue>
          <fpage>89</fpage>
          <lpage>108</lpage>
          <pub-id pub-id-type="doi">10.1007/s10498-017-9311-0</pub-id>
        </element-citation>
      </ref>
      <ref id="B19">
        <label>19.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Yunker</surname><given-names>M.B.</given-names></name>
            <name><surname>Macdonald</surname><given-names>R.W.</given-names></name>
            <name><surname>Ross</surname><given-names>P.S.</given-names></name>
            <name><surname>Johannessen</surname><given-names>S.C.</given-names></name>
            <name><surname>Dangerfield</surname><given-names>N.</given-names></name>
          </person-group>
          <article-title>Alkane and PAH Provenance and Potential Bioavailability in Coastal Marine Sediments Subject to a Gradient of Anthropogenic Sources in British Columbia, Canada</article-title>
          <source>Organic Geochemistry</source>
          <year>2015</year>
          <volume>89-90</volume>
          <fpage>80</fpage>
          <lpage>116</lpage>
          <pub-id pub-id-type="doi">10.1016/j.orggeochem.2015.10.002</pub-id>
        </element-citation>
      </ref>
      <ref id="B20">
        <label>20.</label>
        <element-citation publication-type="book">
          <person-group person-group-type="author">
            <name><surname>Yasakova</surname><given-names>O.N.</given-names></name>
            <name><surname>Makarevich</surname><given-names>P.R.</given-names></name>
          </person-group>
          <source>Current State of Phytoplankton in the North-Eastern Black Sea</source>
          <publisher-loc>Rostov-on-Don</publisher-loc>
          <publisher-name>SSC RAS</publisher-name>
          <year>2023</year>
          <size units="pages">232</size>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
      <ref id="B21">
        <label>21.</label>
        <element-citation publication-type="journal">
          <person-group person-group-type="author">
            <name><surname>Kustenko</surname><given-names>N.G.</given-names></name>
            <name><surname>Imnadze</surname><given-names>N.O.</given-names></name>
          </person-group>
          <article-title>The Effect of Oil and Nitrogen on Phytoplankton in the Eastern Coast of the Black Sea</article-title>
          <source>Ecology of the Sea</source>
          <year>1988</year>
          <volume>29</volume>
          <fpage>73</fpage>
          <lpage>77</lpage>
          <comment>(in Russian)</comment>
        </element-citation>
      </ref>
    </ref-list>
  </back>
</article>
